𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The oxidation of alkanes with dimethyldioxirane; a new mechanistic insight

✍ Scribed by Gregorio Asensio; Rossella Mello; M.Elena Gonzalez-Nuñez; Carmen Boix; Jorge Royo

Book ID
104256722
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
350 KB
Volume
38
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Primary kinetic isotope effects were measured for the oxidation of cyclohexane and methylcyclohexane with DMDO in solution and in the gas phase. These experiments suggest an electrophilic oxygen insertion mechanism for the oxidation of alkanes by DMDO.

📜 SIMILAR VOLUMES

A new route to dithiirane 1-oxides: Oxid
A new route to dithiirane 1-oxides: Oxidation of tetrathiolanes with dimethyldioxirane
✍ Yi-Nan Jin; Akihiko Ishii; Yoshiaki Sugihara; Juzo Nakayama 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 238 KB

Oxidation o:F di-l-adamantyltetrathiolane with dimethyldioxirane (DMD) in dichlommethane and acetone gave di-l-adamantyldithiira~e 1-oxide. Similarly, reaction of ladamanlyl-t-butyltetrathiolane with DMD gave (IRS,3SR)-and (IRS,3RS)-l-edamat~-tbutyldlthiirane 1-oxides. In the reactions, intermediary