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A new route to dithiirane 1-oxides: Oxidation of tetrathiolanes with dimethyldioxirane

✍ Scribed by Yi-Nan Jin; Akihiko Ishii; Yoshiaki Sugihara; Juzo Nakayama

Book ID
104259170
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
238 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

Oxidation o:F di-l-adamantyltetrathiolane with dimethyldioxirane (DMD) in dichlommethane and acetone gave di-l-adamantyldithiira~e 1-oxide. Similarly, reaction of ladamanlyl-t-butyltetrathiolane with DMD gave (IRS,3SR)-and (IRS,3RS)-l-edamat~-tbutyldlthiirane 1-oxides. In the reactions, intermediary formation of teu'athiolane l-oxides was

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The oxidation of alkanes with dimethyldi
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Primary kinetic isotope effects were measured for the oxidation of cyclohexane and methylcyclohexane with DMDO in solution and in the gas phase. These experiments suggest an electrophilic oxygen insertion mechanism for the oxidation of alkanes by DMDO.