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Oxidation of tetrathiolanes: isolation of a vic-disulfoxide, 5-(1-adamantyl)-5-tert-butyltetrathiolane 2,3-dioxide and its decomposition to the dithiirane 1-oxide and ‘S2O’

✍ Scribed by Akihiko Ishii*; Masaaki Nakabayashi; Yi-Nan Jin; Juzo Nakayama*


Book ID
108346717
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
169 KB
Volume
611
Category
Article
ISSN
0022-328X

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Oxidation of cis-3,5-di-tert-alkyl-3,5-d
✍ Hideaki Oshida; Akihiko Ishii; Juzo Nakayama 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 204 KB

Oxidation of cis-3,5-di-tert-alkyl-3,5-diphenyl-1,2,4 -trithiolane with an excess amount of dimethyldioxirane gave the 1,2-dioxide, a vic-disulfoxide, and it was verified that the 1,2-dioxide was formed specifically from one of two stereoisomeric monoxides. The structures of the monoxides and the 1