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Oxidation of cis-3,5-di-tert-alkyl-3,5-diphenyl-1,2,4-trithiolanes: isolation and some properties of the 1-oxides and the 1,2-dioxides

✍ Scribed by Hideaki Oshida; Akihiko Ishii; Juzo Nakayama

Book ID: 104251431
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 204 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)01014-6

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✦ Synopsis

Oxidation of cis-3,5-di-tert-alkyl-3,5-diphenyl-1,2,4

-trithiolane with an excess amount of dimethyldioxirane gave the 1,2-dioxide, a vic-disulfoxide, and it was verified that the 1,2-dioxide was formed specifically from one of two stereoisomeric monoxides. The structures of the monoxides and the 1,2-dioxide were determined by X-ray crystallography.

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