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Diphenyldiselenide-Catalyzed Selective Oxidation of Activated Alcohols with tert -Butyl Hydroperoxide: New Mechanistic Insights

โœ Scribed by van der Toorn, John C.; Kemperman, Gerjan; Sheldon, Roger A.; Arends, Isabel W. C. E.


Book ID
127144806
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
500 KB
Volume
74
Category
Article
ISSN
0022-3263

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CuCl catalyzed selective oxidation of pr
โœ Sreedevi Mannam; G. Sekar ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 130 KB

Direct oxidation of primary alcohols to the corresponding carboxylic acids is performed highly efficiently at room temperature with anhydrous tert-butyl hydroperoxide in the presence of a catalytic amount of easily available CuCl under ligand free conditions in acetonitrile. Benzylic alcohols are mo