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The osmylation of flexible 3-substituted cyclopentenes

✍ Scribed by Giovanni Poli

Book ID: 104212362
Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 266 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)70704-0

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✦ Synopsis

The osmylation of several 3-substituted cyclopentenes has been studied. A preference for 0~04 addition syn to an allylic CHR2 substituent is observed. By contrast, bulkier substiments of type CMeR, give rise to a striking reversal of selectivity. These results are interpreted in terms of the stereodivergent nature of the two differently reactive envelope conformations.

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