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The Osmium Tetroxide Catalyzed Hydroxylation of 1,4-Dimethylenecyclohexanes

โœ Scribed by Murphy, James G.


Book ID
126120521
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
414 KB
Volume
9
Category
Article
ISSN
0022-2623

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๐Ÿ“œ SIMILAR VOLUMES


Osmium tetroxide catalyzed hydroxylation
โœ Rahul Ray; Donald S. Matteson ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 132 KB

Osmium tetroxide catalyzed hydroxylation of sterically hindered olefins proceeds efficiently with trimethylamine N-oxide as oxidizing agent in the presence of pyridine.

A highly stereoselective osmium tetroxid
โœ Gilbert Stork; Michael Kahn ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 196 KB

The hydroxylation of a,B-unsaturated esters catalyzed by osmiumtetroride leads to 3,4-dihydroxy-y-lactones of predictable stereochemistry. We report here on the remarkable stereoselectivity encountered in the osmium tetroxide hydroxylation of E a,l-unsaturated esters bearing a y-hydroxgl function.