𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A highly stereoselective osmium tetroxide-catalyzed hydroxylation of γ-hydroxy α,β-usaturated esters

✍ Scribed by Gilbert Stork; Michael Kahn

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
196 KB
Volume
24
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

The hydroxylation of a,B-unsaturated esters catalyzed by osmiumtetroride leads to 3,4-dihydroxy-y-lactones of predictable stereochemistry.

We report here on the remarkable stereoselectivity encountered in the osmium tetroxide hydroxylation of E a,l-unsaturated esters bearing a y-hydroxgl function.

📜 SIMILAR VOLUMES

ChemInform Abstract: Base-Catalyzed High
ChemInform Abstract: Base-Catalyzed Highly Stereoselective Conversion of γ-Hydroxy-α,β-acetylenic Esters to γ-Acetoxy Dienoates.
✍ Yang Yue; Xiao-Qi Yu; Lin Pu 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Highly Stereoselect
ChemInform Abstract: Highly Stereoselective Epoxidation of α-Methyl-γ-hydroxy-α,β-unsaturated Esters: Rationalization and Synthetic Applications.
✍ Irakusne Lopez; Santiago Rodriguez; Javier Izquierdo; Florenci V. Gonzalez 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 27 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v