๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Notes - Osmium Tetroxide-Catalyzed Periodate Oxidation of Olefinic Bonds

โœ Scribed by Pappo, R.; Allen, Jr., D. S.; Lemieux, R. U.; Johnson, W. S.

Book ID
120546238
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
275 KB
Volume
21
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Osmium tetroxide catalyzed hydroxylation
Osmium tetroxide catalyzed hydroxylation of hindered olefins
โœ Rahul Ray; Donald S. Matteson ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 132 KB

Osmium tetroxide catalyzed hydroxylation of sterically hindered olefins proceeds efficiently with trimethylamine N-oxide as oxidizing agent in the presence of pyridine.

Organic selenoxides as oxidants in osmiu
Organic selenoxides as oxidants in osmium tetroxide catalyzed oxidation of olefins to glycols
โœ A.G. Abatjoglou; D.R. Bryant ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 218 KB

Olefins are catalytically oxidized to glycols by osmium tetroxide in the presence of organic selenoxide cooxidants. Glycols were obtained in good yields from mono-, di-, tri-and tetrasubstituted olefins. Osmium tetroxide is widely used as a catalyst for the cis-dihydroxylation of olefins in conjunct

Asymmetric oxidation of olefins to vicin
Asymmetric oxidation of olefins to vicinal diols with osmium tetroxide
โœ Maritherese Tokles; John K. Snyder ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 251 KB

High levels of asymmetry can be achieved in the osmium tetroxide cis-hydroxylation of olefins by employing (-)-(R,R)-N,N,N',N'-tetramethylcyclohexane-l,2-traos-diamine as a chiral ligand for the osmium. Osmium tetroxide oxidation of olefins is an excellent method for forming vicinal diols under mil