The Open-Chain Trioxide CF3OC(O)OOOC(O)OCF3
✍ Scribed by Stefan von Ahsen; Plácido García; Helge Willner; Maximiliano Burgos Paci; Gustavo A. Argüello
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 141 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0947-6539
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## Abstract Thermal decomposition of bis(trifluoromethyl) peroxydicarbonate has been studied. The mechanism of decomposition is a simple bond fission, homogeneous first‐order process when the reaction is carried out in the presence of inert gases such as N~2~ or CO. An activation energy of 28.5 kca
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
The thermal addition of CF,0sCF3(T 1 to CF2CCl2(E) has been investigated between 49.6 and 69.5"C. The initial pressure of CFJ03CF3 was varied between 7 and 240 torr and that of CF2CC12 between 4 and 600 torr. Four products of formula CF30(E),00CF3, wherej = 1 + 4 are formed. The sum of the products
## Abstract For Abstract see ChemInform Abstract in Full Text.