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Structures of the Trisulfur Oxides S3O and S3O×+: Branched Rings, Not Open Chains

✍ Scribed by Ming Wah Wong; Ralf Steudel

Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

📜 SIMILAR VOLUMES

S3O and S3O+ in the Gas Phase: Ring and
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Oxidation Products of Organic Trisulfane
Oxidation Products of Organic Trisulfanes: Molecular Structures and Energies of Various Isomers of the Dimethyltrisulfane Oxides Me2S3O and Me2S3O and of 1,3–tBu2S3O2
✍ Prof. Dr. Ralf Steudel; Dr. Yana Drozdova 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 898 KB

Ab initio MO calculations (MP2/6-311 G\*\*//HF/6-311 G\*\*) have been performed for several isomers (including rotamers) of Me,S,O and Me,S,O,. MeS(0)SSMe exists as five ro- tamers; the most stable form (la) has a helical backbone CSSSC with S-S bond lengths of 206.0 (S"S") and 212.4 pm (S"S"'). The