## Abstract For Abstract see ChemInform Abstract in Full Text.
S3O and S3O+ in the Gas Phase: Ring and Open-Chain Structures.
โ Scribed by Giulia de Petris; Marzio Rosi; Anna Troiani
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 13 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Abstract
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๐ SIMILAR VOLUMES
The vapor phase structure of ( C H 3 0 ) S [ I ] has been investigated by electron diffraction and ab initio MO calculations, which both result in a C2 symmetry for the most stable geometry, the C, conformer being less stable by about I2 Wlmol. The torsional barrier for rotation about one SO bond wa
than the C-O bond length of CH O in the gas phase by 0.044 A at the 3 MP2raug-cc-pVDZ level of theory. The structure of the CH S y moiety in