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The one-pot conversion of carboxylic acids to aldehydes via activated silyl carboxylates.

✍ Scribed by R.J.P. Corriu; G.F. Lanneau; M. Perrot

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
185 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

The transformation of acids into aldehydes in a one-pot process is performed through the thermal decomposition of pentacoordinated silicon species.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: One-Pot Reduction o
ChemInform Abstract: One-Pot Reduction of Carboxylic Acids via O-Acylisoureas.
✍ J. M. HERBERT; A. T. HEWSON; J. E. PEACE πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 2 views

One-Pot Reduction of Carboxylic Acids via O-Acylisoureas. -A simple one-pot conversion of carboxylic acids to primary alcohols is reported. Functional groups like nitro, amides, and carbamates as well as double bonds are tolerated. Aromatic carboxylic acids like (III) give a mixture of the alcohol