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One pot conversion of car☐ylic acids to aldehydes with DIBAL-H

✍ Scribed by S. Chandrasekhar; M. Suresh Kumar; B. Muralidhar


Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
103 KB
Volume
39
Category
Article
ISSN
0040-4039

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One-pot conversion of carboxylic acids t
✍ Jin Soon Cha; Jin Euog Kim; Se Yeon Oh; Jong Dae Kim 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 245 KB

Carboxylic acids are readily reduced to the corresponding aldehydes in high yields by treatment of acyloxy-9-borabicycloC3.3.llnonanes with lithium 9-boratabicycloL3.3.l]nonane (Li 9-BBNH) at room temperature. Thexylchloroborane-methyl sulfide 2 and thexylbromoborane-methyl sulfide 3