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One-pot conversion of carboxylic acids to aldehydes through treatment of acyloxy-9-borabicyclo[3.3.1]nonanes with lithium 9-boratabicyclo[3.3.1]nonane

✍ Scribed by Jin Soon Cha; Jin Euog Kim; Se Yeon Oh; Jong Dae Kim

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 245 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96568-7

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✦ Synopsis

Carboxylic acids are readily reduced to the corresponding aldehydes in high yields by treatment of acyloxy-9-borabicycloC3.3.llnonanes with lithium 9-boratabicycloL3.3.l]nonane (Li 9-BBNH) at room temperature.

Thexylchloroborane-methyl sulfide 2 and thexylbromoborane-methyl sulfide 3

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