✦ LIBER ✦

Selective reduction of aromatic nitriles to aldehydes by potassium 9-sec-amyl-9-boratabicyclo[3.3.1]nonane

✍ Scribed by Jin Soon Cha; Mal Sook Yoon

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 236 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80481-0

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✦ Synopsis

The title reducing agent (1) reduces aromatic nitriles to the corresponding aldehydes in yields of 60-98 %, while aliphati? nitriles being intact. Transformation of nitriles to aldehydes is of importance in organic synthesis. Numerous methods have been proposed to achieve this objectiveI; however, there have been no report for the selective reduction of only aromatic nitriles to the corresponding aldehydes in the presence of aliphatic nitriles.

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