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Synthesis of a new selective borotritide : [3H]lithium9-boratabicyclo[3.3.1]nonane. Some applications to the preparation of secondary and primary [3H] alcohols

✍ Scribed by Christine Rasset; Bernard Rousseau

Publisher: John Wiley and Sons
Year: 1994
Tongue: French
Weight: 351 KB
Volume: 34
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.2580340605

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✦ Synopsis

Abstract

[^3^H]lithium 9‐boratabicyclo[3.3.1]nonane, at specific activity of 52–55 Ci/mmol, was synthesized by reduction of B‐OMe‐9‐BBN with lithium tritide. Its reducing characteristics were illustrated by the synthesis of [17‐^3^H] estradiol, [2‐^3^H] dihydrotetrabenazine and 1‐(hydroxy[^3^H]methyl)naphtalene, with good radiochemical yields and high specific activities.

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