The one-electron oxidation of 2-methoxy-4,6-di-t-butylphenol
✍ Scribed by J. Petránek; J. Pilař; D. Doskočilova
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 187 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
In connection with a program directed toward the systematic study of red-ox behaviour of phenols substituted with bulky alkyl groups we wish to describe in this communication the oxidation of 2-methoxy-4,6-di-t-butylphenol involving a one-electron transfer. The oxidation was carried out by
📜 SIMILAR VOLUMES
In a previous paper,' we reported a novel base-catalyzed rearrangement of R-peroxyquinol esters derived from 2,6-di-t-butylphenols leading to quinoxyacetic acid derivatives, where the peroxy bond cleaves even below -60 "C. Nature of the peroxy bond cleavage has been remained n
The oxygenation of 4-(N-arylmethyleneamino)-2,6-di-t-butylphenols with Co(Salpr), a five coordinate Co(I1) Schiff base complex, in CH2C12 results in the regioselective hydroperoxylation at the imino carbon to give N-(1-aryl-1-hydroperoxymethyl)-3,5-di-tbutyl-R-benzoquinone mnoimines, which give excl