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Phase transfer catalyzed polymerization of 4-bromo-2,6-dimethylphenol in the presence of a terminating comonomer phenol: 2,4,6-tri-tert-butylphenol or 4-bromo-2,6-di-tert-butylphenol

โœ Scribed by James H. Wang; Virgil Percec


Publisher
Springer
Year
1991
Tongue
English
Weight
415 KB
Volume
25
Category
Article
ISSN
0170-0839

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Synthesis of ฮฑ,ฯ‰-bis(2,6-dimethylphenol)
โœ Virgil Percec; James H. Wang ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Springer ๐ŸŒ English โš– 394 KB

~,o)-Bis(2,6-dimethylphenol)-poly(2,6-dimethyl-1,4-phenylene oxide) (PPO-2OH) was synthesized by the radical-cation phase transfer catalyzed polymerization of 4-bromo-2,6-dimethylphenol (1) in the presence of 2,2-di(4-hydroxy-3,5-dimethylphenyl)propane (2). Copolymerization experiments were performe