Photolysis of 4-bromo-2,6-di-tert-butylphenol in benzene solution
✍ Scribed by G.R. Lappin; J.S. Zannucci
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 120 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The photolysis of a heptane solution of 2,6‐di‐__tert__‐butyl‐4‐__tert__‐butylperoxy‐4‐methyl‐ 2,5‐cyclohexadienone (1) with light of 360–480 nm in the presence of 2,6‐di‐__tert__‐butyl‐4‐methylphenol or 2,4,6‐tri‐__tert__‐butylphenol gives rise to their corresponding phenoxyls in a rea
## Abstract For Abstract see ChemInform Abstract in Full Text.
Radical pairs are formed by photolysis of single crystals of 2,6-di-tert-butyl-4-methylphenol (ionol) (1) or 2,6-di-tert-butylphenol (2 ), doped by several different molecules, and investigated by the EPR method. A possible two-hydrogen-atom transfer is discussed as the photochemical act.