Base-catalyzed decomposition of 3,5-di-t-butyl-4-hydroxybenzoic esters of p-peroxyquinols derived from 2,6-di-t-Butylphenols
β Scribed by A. Nishinaga; K. Nakamura; T. Matsuura
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 197 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In a previous paper,' we reported a novel base-catalyzed rearrangement of R-peroxyquinol esters derived from 2,6-di-t-butylphenols leading to quinoxyacetic acid derivatives, where the peroxy bond cleaves even below -60 "C. Nature of the peroxy bond cleavage has been remained n
π SIMILAR VOLUMES
The selective formation of e-quinols in the Co(Salpr)-catalyzed oxygenation of 4-alkyl-2,6-di-t-butylphenols in MeOH has been found to involve the rate determining reduction of peroxy-R-quinolato Co(II1) complex formed in the initial fast step. An ionic mechanism of the reduction of the O-O bond in
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