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Synthesis of 3-Aryl-2,5-di-tert-butyl-2,4-cyclopentadienones by Base-Catalyzed Oxygenation of 4-Aryl-2,6-di-tert-butylphenols

✍ Scribed by Prof. Dr. Akira Nishinaga; Toshio Itahara; Prof. Dr. Teruo Matsuura; Prof. Dr. Anton Rieker; Dieter Koch


Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
214 KB
Volume
15
Category
Article
ISSN
0044-8249

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A photochemical precursor to a pendant conjugated polyradical has been synthesized, poly [3,5-di-tert-butyl-4-[(2,4,6-tri-tert-butylphenyl)oxalato]phenylacetylene], 3. Irradiation of 3 at 77 K in the solid state at Γ΅ 300 nm yielded poly(3-5-ditert-butyl-2-oxyphenyl acetylene), 2, with 30-40% of the