Base-catalyzed oxygenation of 2,6-di-t-butylanilines: X-ray analysis of 2,4,6-tri-t-butyl-4,5-epoxy-6-hydroxy-2-cyclohexen-1-imine
✍ Scribed by Akira Nishinaga; Toshio Itahara; Koichi Nakamura; Teruo Matsuura; Anton Rieker; Jürgen Bracht; Hans Jörg Lindner
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 634 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
In a previous paper,' we reported a novel base-catalyzed rearrangement of R-peroxyquinol esters derived from 2,6-di-t-butylphenols leading to quinoxyacetic acid derivatives, where the peroxy bond cleaves even below -60 "C. Nature of the peroxy bond cleavage has been remained n
Highly regioselective oxygenation products from 2,6-di-t-butylphenols display interesting chemical behavior under strongly basic conditions, being efficiently utilized for synthesis of hydroquinones, 1 o-benzoquinones, 2 cyclopentadienones, 3 3-hydroxyphenylacetic acids,' cyclopentenones, 5 and B-qu