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The octant rule VI. Circular dichroism of (IS)-4e-Deuteriodamantan-2-one.

✍ Scribed by David A. Lightner; Tsung C. Chang; Joseph Horwitz

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
118 KB
Volume
18
Category
Article
ISSN
0040-4039

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✦ Synopsis

Application of the Octant Rulels3 to interpret n-s* Cotton effects (CE's) of chiral ketones with deuterium perturbers4 has received very little experimental investigation aside from the recent work of Djerassi et al. 4 on chiral (3R)-deuteriocyclopentanone. The latter, despite its conformational mobility, exhibited negative circular dichroism (CD) CE's (AE~D~ = -0.019 at 2SΒ°C

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