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Circular Dichroism of Tricarbonyl(diene)iron Complexes. The Octant Rule Applied to Ketones Perturbed by Remote Fe(CO)3 Groups. Crystal Structure of (±)-Tricarbonyl[(1RS,4RS,5RS,6SR)-C5,6,C-η-(5,6,7,8-tetramethylidene-2-bicyclo[2.2.2]octanone)]iron

✍ Scribed by Raphy Gabioud; Pierre Vogel; Alan A. Pinkerton; Dieter Schwarzenbach

Publisher
John Wiley and Sons
Year
1986
Tongue
German
Weight
655 KB
Volume
69
Category
Article
ISSN
0018-019X

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The transition-metal-carhonyl-induced cyclodimerization of 5,6-dimethylidene-7-oxabicyclo[2.2.l]hept-2-ene is strongly affected by substitution at C( I). While 5,6-dimethylidene-7-oxahicyclo[2.2.l]hept-2-ene-I-methanol (7) refused to undergo [4 + 21-cyclodimerization in the presence of [Fe2(C0)9] in