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The nucleofuge in the pyridinolysis of O-(4-nitrophenyl) S-aryl thio and dithiocarbonates

✍ Scribed by Enrique A. Castro; Margarita E. Aliaga; Marcela Gazitúa; José G. Santos


Book ID
112175609
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
492 KB
Volume
25
Category
Article
ISSN
0894-3230

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Kinetics and mechanism of the aminolysis
✍ Enrique A. Castro; Leonardo Leandro; José G. Santos 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 2 views

The reactions of the title substrate (1) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol-water, at 25.0ЊC, ionic strength 0.2 M (KCl). Under amine excess over the substrate, pseudo-first-order rate coefficients (k obs ) are obtained. Plots of k