The reactions of the title substrate (1) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol-water, at 25.0ЊC, ionic strength 0.2 M (KCl). Under amine excess over the substrate, pseudo-first-order rate coefficients (k obs ) are obtained. Plots of k
✦ LIBER ✦
Kinetics and mechanism of the aminolysis of bis(4-nitrophenyl) carbonate and O -(4-nitropheny) S-(4-nitrophenyl) thio and dithiocarbonate
✍ Scribed by Castro, Enrique A.; Aliaga, Margarita E.; Gazitúa, Marcela; Pavez, Paulina; Santos, José G.
- Book ID
- 121678525
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 235 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0894-3230
- DOI
- 10.1002/poc.3231
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## Abstract The reactions of 4‐methylphenyl 4‐nitrophenyl carbonate (MPNPC) and 4‐methylphenyl 2,4‐dinitrophenyl carbonate (MPDNPC) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol–water, at 25.0°C, ionic strength 0.2 M (KCl). Under amine excess