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Kinetics and mechanism of the aminolysis of bis(4-nitrophenyl) carbonate and O -(4-nitropheny) S-(4-nitrophenyl) thio and dithiocarbonate

✍ Scribed by Castro, Enrique A.; Aliaga, Margarita E.; Gazitúa, Marcela; Pavez, Paulina; Santos, José G.


Book ID
121678525
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
235 KB
Volume
27
Category
Article
ISSN
0894-3230

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📜 SIMILAR VOLUMES


Kinetics and mechanism of the aminolysis
✍ Enrique A. Castro; Leonardo Leandro; José G. Santos 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 2 views

The reactions of the title substrate (1) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol-water, at 25.0ЊC, ionic strength 0.2 M (KCl). Under amine excess over the substrate, pseudo-first-order rate coefficients (k obs ) are obtained. Plots of k

Kinetics and mechanism of the aminolysis
✍ Enrique A. Castro; Monica Andujar; Paola Campodonico; José G. Santos 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB

## Abstract The reactions of 4‐methylphenyl 4‐nitrophenyl carbonate (MPNPC) and 4‐methylphenyl 2,4‐dinitrophenyl carbonate (MPDNPC) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol–water, at 25.0°C, ionic strength 0.2 M (KCl). Under amine excess