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Kinetics and mechanism of the aminolysis of 4-nitrophenyl dithioacetate

✍ Scribed by Castro, Enrique A.; Ibanez, Fernando; Santos, Jose G.; Ureta, Carmen

Book ID
126905423
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
605 KB
Volume
57
Category
Article
ISSN
0022-3263

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Kinetics and mechanism of the aminolysis
Kinetics and mechanism of the aminolysis of p-nitrophenyl N-phenylcarbamates
✍ Han Joong Koh; Ok Sun Kim; Hai Whang Lee; Ikchoon Lee πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 108 KB πŸ‘ 2 views

Kinetic studies of the reactions of p-nitrophenyl N-phenylcarbamates with benzylamines were carried out in acetonitrile at 25β€’0 Β°C. Second-order (k 2 ) and third-order (k 3 ) rate constants were observed for all the Y-substituted carbamates except for Y = m Οͺ Cl. The relatively large magnitude of X