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Kinetics and Mechanism of the Aminolysis of Phenyl and 4-Nitrophenyl Chloroformates in Aqueous Solution

✍ Scribed by Castro, Enrique A.; Ruiz, Maria G.; Salinas, Sandra; Santos, José G.

Book ID
127106703
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
49 KB
Volume
64
Category
Article
ISSN
0022-3263

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Kinetics and mechanism of the aminolysis
Kinetics and mechanism of the aminolysis of O-phenyl 4-nitrophenyl dithiocarbonate in aqueous ethanol
✍ Enrique A. Castro; Leonardo Leandro; José G. Santos 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 2 views

The reactions of the title substrate (1) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol-water, at 25.0ЊC, ionic strength 0.2 M (KCl). Under amine excess over the substrate, pseudo-first-order rate coefficients (k obs ) are obtained. Plots of k