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Kinetics and mechanism of the aminolysis of phenyl thionoacetate in aqueous solution

✍ Scribed by Castro, Enrique A.; Ibanez, Fernando; Santos, Jose G.; Ureta, Carmen

Book ID
125942234
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
535 KB
Volume
58
Category
Article
ISSN
0022-3263

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## Abstract The reactions of secondary alicyclic amines with the title substrate (PDTC) are subjected to a kinetic study in 44 wt.% aqueous ethanol, 25.0Β°C, ionic strength 0.2 M (KCl). Pseudo‐first‐order rate coefficients (__k__~obs~) are found under amine excess. Linear plots of [__N__]/__k__~obs~