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Kinetics and Mechanism of Aminolysis of Phenyl Acetates in Aqueous Solutions of Poly(ethylenimine)

✍ Scribed by Arcelli, Antonio; Concilio, Carlo

Book ID: 115479486
Publisher: American Chemical Society
Year: 1996
Tongue: English
Weight: 249 KB
Volume: 61
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo9514681

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## Abstract The reactions of secondary alicyclic amines with the title substrate (PDTC) are subjected to a kinetic study in 44 wt.% aqueous ethanol, 25.0°C, ionic strength 0.2 M (KCl). Pseudo‐first‐order rate coefficients (__k__~obs~) are found under amine excess. Linear plots of [__N__]/__k__~obs~