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The new fluorescent probe in the process of methyl methacrylate polymerization

✍ Scribed by Zheng-Lin Yan; Shi-Kang Wu


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
324 KB
Volume
96
Category
Article
ISSN
1010-6030

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✦ Synopsis


On the basis of the preparation of two 2-pyrazoline compounds, 1,5-diphenyl-3-nitrophenyl-2-pyrazoline and 1,5-diphenyl-3-styryl-2-t~yrazoline, the steady-state photophysical properties have been studied. Results indicated that there is a close relationship between a good l:uorescence probe and the intramolecular charge transfer extent, and the strong intramolecular charge transfer is essential for a good I tuorescence probe.


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## Abstract Dialkyl iodomethylmalonates in the presence of tetrabutylammonium iodide initiate the polymerization of methyl methacrylate, but not of methyl acrylate or acrylonitrile. Typically, at 60Β°C in 1,3‐dimethyltetrahydro‐2‐1__H__‐pyrimidone (DMPU) as the solvent, poly(methyl methacrylate (PMM