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Rate constants in the polymerization of methyl methacrylate

✍ Scribed by U.S Nandi

Publisher
Elsevier Science
Year
1957
Weight
135 KB
Volume
12
Category
Article
ISSN
0095-8522

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Equilibria in the anionic polymerization
Equilibria in the anionic polymerization of methyl methacrylate, 1. Chain-length dependence of the rate and equilibrium constants
✍ MΓΌller, Axel H. E. ;Lochmann, LubomΓ­r ;Trekoval, JiΕ™i πŸ“‚ Article πŸ“… 1986 πŸ› Wiley (John Wiley & Sons) βš– 318 KB

The rate constants of polymerization and cyclization and the equilibrium constants of polymerization are calculated from kinetic data of the anionic oligomerization of methyl methacrylate initiated by methyl a-lithioisobutyrate in THF at 25 "C, and of the "disproportionation" of living oligomers. Th