Miniemulsions of methyl methacrylate with sodium lauryl sulfate as the surfactant and dodecyl mercaptan (DDM) as the cosurfactant (or hydrophobe) were prepared and polymerized. The emulsions were of a droplet size range common to miniemulsions and exhibited long-term stability (greater than 3 months
✦ LIBER ✦
n-Dodecyl mercaptan transfer constant in polymerization of methyl methacrylate
✍ Scribed by F. Jahanzad; M. Kazemi; S. Sajjadi; F.Afshar Taromi
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 229 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0032-3861
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## Abstract Using the Mayo and the Clay‐Gilbert method, the transfer rate coefficient of α‐thioglycerol (TG) was determined at 50°C for the polymerization of methyl methacrylate (MMA) in a 3 mol · L^−1^ tetrahydrofuran solution using different amounts of 2,2′‐azoisobutyronitrile (AIBN) as initiator