The efficiency of the neutralization step in neutralization-reionization mass spectrometry was examined in detail. Collisionat charge exchange between a large number of common organic and inorganic cations and He, N, , H, , SF,, CH, , Xe, 0, , cyclo-C,H, and NO revealed that the energy defect for t
The neutralization—reionization mass spectrum of C+60
✍ Scribed by Thomas Wong; Johan K. Terlouw; Thomas Weiske; Helmut Schwarz
- Book ID
- 103602332
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 399 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0168-1176
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Neutralization of a beam of vinylidene anions, [ CH,-C] -., by xenon gives rise to a stable CIHz species, having a lifetime 2 0.4 us. Re-ionization with oxygen generates a species which is identified byits collisional activation mass spectrum as the vinylidene radical cation, [CH+Z] +..
## Abstract For Abstract see ChemInform Abstract in Full Text.
Helm, H. Nath, unpublished results. [7] X-ray structure analysis of 3a: C22H26BCI,NTi.0.5CH2C12, M=547.5; single crystal 0.22 x 0.30 x 0.30 mm'; monoclinic, P2,/n, a = 10.672(4), b = 12.079(3), ~=21.179(3) A, b= 101.93(3)", V=2671 A' , Z = 4 , pLIClrd=1.36 g cm-'. p(MoKa)=8.33 cm-', 28=2-50" in h k