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Ethylenedithione (C2S2): Generation and Characterization by Neutralization-Reionization Mass Spectrometry

✍ Scribed by Dipl.-Chem. Detlev Sülzle; Prof. Dr. Helmut Schwarz

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
322 KB
Volume
27
Category
Article
ISSN
0044-8249

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✦ Synopsis

Helm, H. Nath, unpublished results.

[7] X-ray structure analysis of 3a: C22H26BCI,NTi.0.5CH2C12, M=547.5; single crystal 0.22 x 0.30 x 0.30 mm'; monoclinic, P2,/n, a = 10.672(4), b = 12.079(3), ~=21.179(3) A, b= 101.93(3)", V=2671 A' , Z = 4 , pLIClrd=1.36 g cm-'. p(MoKa)=8.33 cm-', 28=2-50" in h k i l , 3970 measured reflections, 3295 observed reflections with 12 2.5o(f); empirical absorption correction, anisotropic refinement of the non-hydrogen atoms, H atoms of the CH, groups and of a CH2 group included in the refinement with a riding model, those of the fluorenyl unit were freely refined, U , , fixed. The CH2C12 molecule was taken into consideration in the refinement with half occupation (without H atoms). R=0.103, R,. = 0.1 I4 [9b].

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