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Transient Intermediates of Chemical Reactions by Neutralization—Reionization Mass Spectrometry

✍ Scribed by Frantisek Turecek

Publisher
John Wiley and Sons
Year
2004
Weight
54 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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Neutralization of a beam of vinylidene anions, [ CH,-C] -., by xenon gives rise to a stable CIHz species, having a lifetime 2 0.4 us. Re-ionization with oxygen generates a species which is identified byits collisional activation mass spectrum as the vinylidene radical cation, [CH+Z] +..