The near-infrared Y 2 + -X 2 transition of the diatomic molecule CuSe was observed for the first time. A King-type carbon tube furnace was used to produce the gas phase of the CuSe molecules. The Fourier transform spectrometer associated with the National Solar Observatory, Kitt Peak, Arizona was us
The Near-InfraredY2Σ+–X2Π Transition of CuS
✍ Scribed by L.C. O'Brien; M. Dulick; S.P. Davis
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 75 KB
- Volume
- 195
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The near-infrared electronic transition of CuS has been observed for the first time. The spectrum of the Y 2 ⌺ ϩ -X 2 ⌸ transition, labeled by analogy with the CuO near infrared electronic transition, was recorded with the Fourier transform spectrometer associated with the McMath-Pierce Solar Telescope, Kitt Peak, Arizona. The excited CuS molecules were produced in a King-type carbon tube furnace operating at 1900°C and at a total pressure of approximately 400 Torr. The electronic transition energy and vibrational constants for the Y 2 ⌺ ϩ state of 63 Cu 32 S are presented.
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