THE NATURE OF THE INTERMEDIATE IN THE SOLVOLYSIS OF NORBORNYL DERIVATIVES 1,2
β Scribed by Roberts, John D.; Lee, C. C.
- Book ID
- 121271408
- Publisher
- American Chemical Society
- Year
- 1951
- Tongue
- English
- Weight
- 251 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Numerous studies have shown the P-norbornyl cation to exhibit a remarkable degree of exo-stereospecificity upon nucleophilic substitution. 1 2-4 Some recent work, however, has shown this stereospecificity to be lost upon incorporation of an electron withdrawing substituent located either 01 or S to
## a b s t r a c t Interesting norbornane-fused tetrahydrofurans, with an additional synthetically-valuable vicinal dioxysubstitution in the norbornane skeleton, are enantiospecifically obtained in high yield from epimeric camphor-derived 3-endo-bromomethyl-substituted spiroepoxidic 1-norbornyl tr