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The solvolysis of bridgehead-substituted exo-2-norbornyl bromides

✍ Scribed by Wilt, James W.; Wagner, William J.

Book ID: 127048651
Publisher: American Chemical Society
Year: 1968
Tongue: English
Weight: 867 KB
Volume: 90
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01024a034

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## Abstract The solvolysis rate constants __k__ for the 6‐__endo__‐substituted 2‐__exo__‐norbornyl toluenesulfonates **7** have been determined. Values of log__k__ correlate well with the respective inductive constants of the substitutents except when the latter are nucleophilic and therefore lead