Solvolysis of crowded 2-adamantyl derivatives: comparison with the 2-norbornyl system
โ Scribed by D. Faulkner; M.A. McKervey; D. Lenoir; C.A. Senkler; P.v.R. Schleyer
- Book ID
- 104213906
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 226 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The synthesis .from l4CC0, of various endo-and exo-3-I4Cdehydro-2-norbornyl and 2-norbornyl derivatives, suitable for use in isotopic scrambling studies, is described. ## INTRODUCTION. In the original work of Roberts and coworkers ( l , 2, on the solvolyses of exo-and end0-2,3-~~C,-2-norbornyl br
The solvolysis rates and products of the tertiary 2-methyl-2-exo-and -2-endonorbornyl 2,4-dinitrophenyl ethers 1 and 2, (X = 2,4-(NO,),C,H,O) have been determined. The different sensitivities of the rates of these ethers to the inductive effect of substituents at C(6) indicate that graded bridging o