The nature of molecular oxygen binding and activation in Mn-O2complex
โ Scribed by G. I. Kobzev; D. G. Urvaev
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2006
- Tongue
- English
- Weight
- 120 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-4766
No coin nor oath required. For personal study only.
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The interaction of reduced transition-metal porphyrins [e.g. PMn (II), PFe (II), PCo (II)] with oxygen species (ยท O ~2~ยท, H ~2~^+^ O ยท/ HO ยท, HOO ยท, ยท O ยท) involves radical/radical coupling to form covalent bonds. Coordinately unsaturated iron(II) porphyrins form two sigma bonds with ยท O ~2~ยท(-ฮ G
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