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ChemInform Abstract: The Nature of the Bonding Between Metalloporphyrins (Fe(II), Co(II), Mn(II)) and Oxygen Species (×O-O×, H2+O×/HO×, HOO×,×O×)

✍ Scribed by Donald T. Sawyer

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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The interaction of reduced transition-metal porphyrins [e.g. PMn (II), PFe (II), PCo (II)] with oxygen species (· O ~2~·, H ~2~^+^ O ·/ HO ·, HOO ·, · O ·) involves radical/radical coupling to form covalent bonds. Coordinately unsaturated iron(II) porphyrins form two sigma bonds with · O ~2~·(-Δ G

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