✦ LIBER ✦

Preparation and catalysis of NaY-encapsulated Mn(III) Schiff-base complex in presence of molecular oxygen

✍ Scribed by Rong-Min Wang; Hui-Xia Feng; Yu-Feng He; Chun-Gu Xia; Ji-Shuan Suo; Yun-Pu Wang

Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 229 KB
Volume: 151
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(99)00256-3

No coin nor oath required. For personal study only.

✦ Synopsis

The new NaY zeolite DMY , whose cages' size had been expanded, was used as supports for encapsulating the large Schiff-base complexes. The catalysts were used in the aerobic epoxidation of 1-octene. The catalyst showed high activity and selectivity for the substrate and products. These catalysts proved to be more active than other kind of metal ion or supports. The effect of temperature, organic acid or base, and the amount of catalyst was discussed.

📜 SIMILAR VOLUMES

Preparation and catalysis of DMY and MCM

Preparation and catalysis of DMY and MCM-41 encapsulated cationic Mn(III)–porphyrin complex

✍ Zhen Li; Chun-Gu Xia; Xiao-Ming Zhang 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 228 KB

(Schiff-Base)Mn(III)-Catalyzed Hydroxyla

(Schiff-Base)Mn(III)-Catalyzed Hydroxylation of α,β-Unsaturated Esters Using Molecular Oxygen in the Presence of Metal Hydrides.

✍ Jong Seok Baik; Sung-bin Han; Nam Ho Lee 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 19 KB 👁 1 views

Development of Mn(III)(Schiff Base) Comp

Development of Mn(III)(Schiff Base) Complexes for the Catalyst of Olefin Oxygenation to Alcohols in the Presence of NaBH4.

✍ Nam Ho Lee; Jong Chul Byun; Jong Seok Baik; Chung-Hun Han; Sung-bin Han 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 98 KB 👁 2 views

ChemInform Abstract: Preparation of a Ze

ChemInform Abstract: Preparation of a Zeolite X-Encapsulated Copper(II) Chloride Complex and Its Catalysis for Liquid-Phase Oxygenation of Enamines in the Presence of Molecular Oxygen.

✍ Kohki Ebitani; Kohji Nagashima; Tomoo Mizugaki; Kiyotomi Kaneda 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

The preparation of some polystyrene-supp

The preparation of some polystyrene-supported porphyrinatoiron(III) and their catalysis in hydroxylation of cyclohexane with molecular oxygen

✍ Zhan-Liang Liu; Jin-Wang Huang; Liang-Nian Ji 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 350 KB

Some polystyrene-supported porphyrinatoiron( III) with different stereostructure were prepared using a new method and characterized by EA, UV-Vis,IR and EPR. Their catalytic activities in hydroxylation of cyclohexane with molecular oxygen have been found to be high compared with corresponding non-su

ChemInform Abstract: Catalysis of a Hydr

ChemInform Abstract: Catalysis of a Hydroxyapatite-Bound Ru Complex: Efficient Heterogeneous Oxidation of Primary Amines to Nitriles in the Presence of Molecular Oxygen.

✍ Kohsuke Mori; Kazuya Yamaguchi; Tomoo Mizugaki; Kohki Ebitani; Kiyotomi Kaneda 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views