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The molecular Zeeman effect in PH2D and PHD2 and the molecular g-values, magnetic susceptibilities, and molecular quadrupole moment in PH3

✍ Scribed by S.G. Kukolich; W.H. Flygare

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
426 KB
Volume
7
Category
Article
ISSN
0009-2614

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✦ Synopsis

The Zeeman effect was tibserved for two rotational transitions in PH.,D and two robtional transitions The combined results were analyzed to determine the ratio of g-value to rotational constant The results areg;, /G ,,= -(0.0279 5 0.001s) x ceptibility tensor and the second moments of the electroni c charge distribution are given and compared to NH3.

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NH3 and PH3 molecular quadrupole moments
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Molecular &man effect data for NH, and PH, was reviewed and reanalyzed to obtain molecular quadrupole moments. Since the signs of molecular g-values were not directly measured, molecular quadrupole moments were also calculated using ab initio SCF programs to remove ambiguities in the signs of g-valu

Molecular g-value, magnetic susceptibili
Molecular g-value, magnetic susceptibility anisotropy, and molecular quadrupole moment in OCSe
✍ R.L. Shoemaker; W.H. Flygare πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 English βš– 351 KB

The molecular Zeemsn effect has been observed in 160 1% \*@Se and 160 1% 76Se. The molecular gvalue zzreg& = -0.01952 f 0.0001 snd gi= -0.01969 \* O.OOOt\_respectiveIy. The magnetic susceptibility snisotropy, which is ~~e~ndent of the center of mass, is x~-x~, = (IO.06 \* 0.18 x 10'6 erg/:/E2 mole.