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NH3 and PH3 molecular quadrupole moments and the signs of molecular g-values

โœ Scribed by J. Combariza; W.R. Salzman; S.G. Kukolich

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
166 KB
Volume
167
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Molecular &man effect data for NH, and PH, was reviewed and reanalyzed to obtain molecular quadrupole moments. Since the signs of molecular g-values were not directly measured, molecular quadrupole moments were also calculated using ab initio SCF programs to remove ambiguities in the signs of g-values. For NHs, &(measured)= -3.4(4) buckir@am and &(calculated) = -2.8 buckingham. For PHs, &(measured)= -2.3( 12) buckingham and Q,(calculated) = -2.4 buck-

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