Molecular g-value, magnetic susceptibility anisotropy, and molecular quadrupole moment in OCSe
β Scribed by R.L. Shoemaker; W.H. Flygare
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 351 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The molecular Zeemsn effect has been observed in 160 1% *@Se and 160 1% 76Se. The molecular gvalue zzreg& = -0.01952 f 0.0001 snd gi= -0.01969 * O.OOOt_respectiveIy. The magnetic susceptibility snisotropy, which is ~~e~ndent of the center of mass, is x~-x~, = (IO.06 * 0.18 x 10'6 erg/:/E2 mole.
. The zuolecukr qus&xpoIe moment in 1%12~ *%e ie Q,, = -f&32 i 0.24) x 10'2 6 esu cm2, An upper Ii&it ie giv& for the nuclear magnetic ehieiding anigotzropy at the 7?3a nudeus iu W 77Se.
π SIMILAR VOLUMES
The molectilar Zeeman effect has been observed in FC-'CH under high resolution. The data yield the molecular g-value of gr = -0.0077 t 0.0002 and magnetic susceptibilitv anisotropy of xL -x,, = (0.861 z L 0.018) x 10-29 er,aiG%. The combination of these two results gives the molecular quadrupoIe mom
The Zeeman effect was tibserved for two rotational transitions in PH.,D and two robtional transitions The combined results were analyzed to determine the ratio of g-value to rotational constant The results areg;, /G ,,= -(0.0279 5 0.001s) x ceptibility tensor and the second moments of the electroni