The molecular vibration-rotation Hamiltonian in the Bargmann-Hilbert space
โ Scribed by Y. Ben-Aryeh
- Book ID
- 103239948
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 826 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-4073
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๐ SIMILAR VOLUMES
The stretching vibration-rotation Hamiltonian of tetrahedral molecules is derived in the local-mode model. The result shows that the effective rotational Hamiltonian of a local-mode state gives rise to symmetric-top rotational energy levels, which are quantitatively in good agreement with experiment
Crawford's A matrix in the theory of molecular vibrations is, in a sense, the inverse of Wilson's B matrix, but is not unique because B is rectangular. We consider the general form of A and then use the Eckart conditions to obtain the solution A = M(-1)B(T)G(-1), which has been widely used. Although