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The molecular vibration-rotation Hamiltonian in the Bargmann-Hilbert space

โœ Scribed by Y. Ben-Aryeh


Book ID
103239948
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
826 KB
Volume
28
Category
Article
ISSN
0022-4073

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๐Ÿ“œ SIMILAR VOLUMES


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The stretching vibration-rotation Hamiltonian of tetrahedral molecules is derived in the local-mode model. The result shows that the effective rotational Hamiltonian of a local-mode state gives rise to symmetric-top rotational energy levels, which are quantitatively in good agreement with experiment

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Crawford's A matrix in the theory of molecular vibrations is, in a sense, the inverse of Wilson's B matrix, but is not unique because B is rectangular. We consider the general form of A and then use the Eckart conditions to obtain the solution A = M(-1)B(T)G(-1), which has been widely used. Although