The pure rotational spectra of five isotopic species of thiophosphoryl chloride, SPCl 3 , have been examined in detail in the frequency range 26 -110 GHz. This study has shown that the frequencies previously reported for the rotational transitions of three symmetric-top species of SPCl 3 in the grou
The Molecular Constants of12CH3I in the Ground andv6= 1 Excited Vibrational State
✍ Scribed by S. Carocci; A. Di Lieto; A. De Fanis; P. Minguzzi; S. Alanko; J. Pietilä
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 173 KB
- Volume
- 191
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
A set of 26 new measurements have been recorded by a Doppler-free double-resonance technique, with a relative accuracy of about 10(-8). These data are combined to previous FTIR measurements to refine the molecular constants of 12CH3I. All the available literature data have been revisited, a few assignments updated, and some frequencies changed according to new laser standards. A simultaneous fit to all the measurements of infrared, microwave, and radiofrequency transitions produced an improved set of parameters, independent of previously determined constants. Copyright 1998 Academic Press.
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