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Millimeter and Submillimeter-Wave Spectrum of Hydrogen Peroxide in the Ground andv3= 1 Vibrational States

✍ Scribed by Douglas T. Petkie; Thomas M. Goyette; Frank C. De Lucia; Paul Helminger; S.P. Belov; G. Winnewisser

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 281 KB
Volume: 192
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1998.7651

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✦ Synopsis

The first measurements of the millimeter-and submillimeter (mm/submm)-wave rotational-torsional transitions in the v 3 ϭ 1 ground torsional state (n ϭ 0) of hydrogen peroxide are reported. The 149 newly measured transitions extend from 72 to 623 GHz in frequency and up to J ϭ 32 and K a ϭ 3 in rotational quantum number. Additional measurements in the ground vibrational and torsional state around 1 THz are also reported. These data, along with all previously published microwave, mm/submm-wave, and far infrared data in the ground and v 3 ϭ 1 vibrational state, along with recent infrared measurements, have been fitted simultaneously to their respective experimental uncertainties using a multi-state Hamiltonian that includes Fermi-and Coriolis-type interactions.

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